Green Synthesis and High-efficiency Method for Reduced Graphene Oxide by Urtica Dioica Extracts

  • Negar Javanmardi School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology
  • Dr Nooredin Goodarzian, Associated Professor Chemistry Department, Islamic Azad University, Shiraz Branch, Shiraz, Iran
  • Mingzhu Xia, Professor School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology
  • Fengyun Wang, Professor School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology
Keywords: Green synthesis, Urtica Dioica, Reduced graphene oxide, Graphene oxide

Abstract

There are various methods to produce nanoparticles, but utilizing the plants for nanoparticle synthesis due to their environmentally friendly nature and low cost is very highly considered. Here, we report the green synthesis of reduced graphene oxide with high efficiency using extracts of Urtica Dioica for the first time. In this study, Urtica Dioica extracts were utilized as a reducing material for the synthesis of nano-graphene oxide. The reduced graphene oxide was analyzed for the determination of size and structural properties using XRD, FTIR, Raman spectra, and TEM

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References

[1] Cobb MD, Macoubrie J.. Public perceptions about nanotechnology: Risks, Benefits and trust. J Nano Res. 2004.6(4):395-405, DOI: 10.1007/s11051-004-3394-4.
[2] Dowling AP. Development of nanotechnologies. Materials Today. 2004. 7:30–35.
[3] Gaskell G, Eyck T Ten, Jackson J. From our readers Public Attitudes to Nanotechnology. 3:2004.
[4] Marchant GE, Sylvester DJ. Transnational models for regulation of nanotechnology.
Journal of Law, Medicine and Ethics. 2006. 34:714–725.
[5] Woodrow Wilson International Center for Scholars. A nanotechnology consumer products inventory. 2007.
[6] Caragiu M, Finberg S. Alkali metal adsorption on graphite: a review. Journal of Physics: Condensed Matter. 2005. 17:R995.
[7] Hövel H, Barke I. Morphology and electronic structure of gold clusters on graphite: Scanning-tunneling techniques and photoemission. Progress in Surface Science. 2006.81:53–111.
[8] Metois JJ, Heyraud JC, Takeda Y. Experimental conditions to obtain clean graphite surfaces. Thin Solid Films. 1978. 51:105–117.
[9] Hummers WS, Offeman RE. Preparation of Graphitic Oxide. Journal of the American Chemical Society. 1958.80:1339.
[10] Lerf A, He H, Forster M, Klinowski J. Structure of Graphite Oxide Revisited ‖. The Journal of Physical Chemistry B. 1998. 102:4477–4482.

[11] Yongchen Liu, Application of graphene oxide in water treatment, November, IOP Conference Series Earth and Environmental Science2017. 94(1):012060.
DOI: 10.1088/1755-1315/94/1/012060.
[12] Dreyer DR, Park S, Bielawski CW, Ruoff RS. The chemistry of graphene oxide.
Chemical Society reviews. 2010. 39:228–240.
[13] Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen SBT, Ruoff RS. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon. 2007. 45:1558–1565.
[14] Park S, Ruoff RSChemical methods for the production of graphenes. Nature nanotechnology. . 2009. 4:217–24
[15] Sun Z, Yan Z, Yao J, Beitler E, Zhu Y, Tour JMGrowth of graphene from solid carbon sources. Nature. . 2010. 468:549–552.
[16] Andrew T. Smith, Anna MarieLaChance, Songshan Zeng, Bin Liu, Luyi Sun, Synthesis, properties, and applications of graphene oxide/reduced graphene oxide and their nanocomposites, Nano Materials Science, Volume 1, Issue 1, March 2019, Pages 31-47

[17] Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH. Large-scale pattern growth of graphene films for stretchable transparent electrodes.
Nature. 2009. 457:706–710.
[18] Jia L, Yu S, Jiang Y, Wang C. Electrochemical deposition of diluted magnetic semiconductor ZnMnSe2on reduced graphene oxide/polyimide substrate and its properties.
Journal of Alloys and Compounds. 2014. 609:233–238.
[19] Shakir I. High Energy Density based Flexible Electrochemical Supercapacitors from Layer-by-Layer Assembled Multiwall Carbon Nanotubes and Graphene. Electrochimica Acta.
. 2014.129:396–400.
[20] Dato A, Radmilovic V, Lee Z, Phillips J, Frenklach MSubstrate-Free Gas-Phase Synthesis of Graphene Sheets. Nano Letters. . 2008. 8:2012–2016.
[21] Wu Z-S, Ren W, Gao L, Liu B, Jiang C, Cheng H-MSynthesis of high-quality graphene with a pre-determinedvnumber of layers. CARBON. . 2009. 47:493 – 499.
DOI: 10.1039/B917103G
[22] Zhu BY, Murali S, Cai W, Li X, Suk JW, Potts JR, Ruoff RSGraphene and Graphene Oxide : Synthesis , Properties , and Applications. . 2010. :3906–3924.
[23 ] Bhuwan Chandra Joshi, Minky Mukhija and Ajudhia Nath Kalia, Pharmacognostical review of Urtica dioica L., International Journal of Green Pharmacy, 2014, 8(4):201-209 DOI:
10.4103/0973-8258.142669.
[24] Bassett IJ; Crompton CW Woodland DW, The family Urticaceae in Canada. Canadian Journal of Botany, 1974. 52(3):503-516.
[25] Urtica dioica - L". Plants for a Future.. Retrieved 23 April.Bayer CropScience, Urtica dioica. http://www.cropscience.bayer.com/en/ProductsandInnovation/Crop-Compendium/Pests-Diseases-Weeds/Weeds/Urtica-dioica.aspx. 2015. 2012.2018
[26] Bassett IJ; Crompton CW; Woodland DW, The biology of Canadian weeds. 21.
Urtica dioica L. Canadian Journal of Plant Science, 1977.57(2):491-498.
[27] Per Brodal The Central Nervous System: Structure and Function. Oxford University Press US. p. 170. Retrieved 22 September 2010 ISBN 978-0-19-538115-3..
[28] Lukešová, Hana "Identifying plant fibre textiles from Norwegian Merovingian Period and Viking Age graves: The Late Iron Age Collection of the University Museum of Bergen". Journal of Archaeological Science: Reports. (June 2017). 13: 281–285. doi:10.1016/j.jasrep.2017.03.051.
[29] Lutomski, Jerzy; Speichert, Henryk "Die Brennessel in Heilkunde und Ernährung".
Pharmazie in Unserer Zeit (in German). (1983). 12 (6): 181–186. doi:10.1002/pauz.19830120602.
[30] Guil-Guerrero, J.L; Rebolloso-Fuentes, M.M; Isasa, M.E.Torija "Fatty acids and carotenoids from Stinging Nettle (Urtica dioica L.)". Journal of Food Composition and Analysis. (2003). 16 (2): 111–119. doi:10.1016/S0889-1575(02)00172-2.
[31] USDA National Nutrient Database: raw carrot". Retrieved 28 November 2015.
[32] Loetscher, Y; Kreuzer, M; Messikommer, R.E "Utility of nettle (Urtica dioica) in layer diets as a natural yellow colorant for egg yolk". Animal Feed Science and Technology. (2013). 186 (3–4): 158–168. doi:10.1016/j.anifeedsci.2013.10.006.
[33] T. Chen and R. CheungMechanical properties of graphene, Graphene Science Handbook, vol. ,2016, 90, pp. 3–16.
[34] Hudson T. Hartmann, Dale E. Kester, Fred T. Davies Jr., Robert L. Geneve, Hartmann & Kester's Plant Propagation: Principles and Practices (8th Edition) , Pearson Publisher, 8 edition, 2010, ISBN-13: 978-0135014493, ISBN-10: 0135014492.
[35] NOVIKOV, PG and KAPELEV I. Propagation of some essential oil bearing plants of the labiatae family by softwood cuttings. Byulletin Gosudarstvenogo Nikitskogo Botanicheskogo Sada. 1984.50:60–63.
[36] Fan X, Peng W, Li Y, Li X, Wang S, Zhang G, Zhang F. Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation.
Advanced Materials. 2008. 20:4490–4493.
[37] Pei, S.; Cheng HM. The Reduction of Graphene Oxide. Carbon. 2012. 50:3210–3228.
[38] Akhavan O, Ghaderi E. Escherichia coli bacteria reduce graphene oxide to bactericidal graphene in a self-limiting manner, Carbon, 2012.50(5):1853–1860.
[39] Elvin Aliyev, Volkan Filiz, Muntazim M. Khan, Young Joo Lee, Clarissa Abetz, and Volker Abetz, Structural Characterization of Graphene Oxide: Surface Functional Groups and Fractionated Oxidative Debris, Nanomaterials (Basel). 2019 Aug; 9(8): 1180.
[40] Wang Y, Shi Z, Yin J. Facile Synthesis of Soluble Graphene via a Green Reduction of Graphene Oxide in Tea Solution and Its Biocomposites. ACS Applied Materials & Interfaces. 2011.3:1127–1133.
[41] Cui P, Lee J, Hwang E, Lee HOne-pot reduction of graphene oxide at subzero temperatures. Chemical communications (Cambridge, England). 2011. 47:12370–2.
[42] Dandan Hou, Qinfu Liu, Hongfei Cheng, Hao Zhang, Sen Wang, Green reduction of graphene oxide via Lycium barbarum extract, Journal of Solid State Chemistry, 2017,246, 351–356.
[43] Thakur S, Karak N, Green reduction of graphene oxide by aqueous phytoextracts, Carbon 50, , 2012.5331–5339.
[44] F. Perreault, A. Fonseca De Faria, and M. Elimelech, Environmental applications of graphene-based nanomaterials, Chemical Society Reviews, 2015, 44: 16, 5861–5896.
[45] M. F. Zainuddin, N. H. Nik Raikhan, N. H. Othman, and W. F. H. Abdullah, “Synthesis of reduced Graphene Oxide (rGO) using different treatments of Graphene Oxide (GO),”IOP Conference Series: Materials Science and Engineering, 2018,358: 6.
[46] Bayisa Meka Chufa , Bedasa Abdisa Gonfa,Teketel Yohannes Anshebo and Getachew Adam Workneh, , A Novel and Simplest Green Synthesis Method of Reduced Graphene Oxide Using Methanol Extracted Vernonia, Amygdalina: Large-Scale Production, Advances in Condensed Matter Physics, 2021. Article ID 6681710, doi.org/10.1155/2021/6681710.
[47] Vatandost E, Ghorbani-HasanSaraei , Chekin , Naghizadeh Raeisi , Seyed-Ahmad Shahidi, Green tea extract assisted green synthesis of reduced graphene oxide: Application for highly sensitive electrochemical detection of sunset yellow in food products, Food Chemistry, 2020, 6:100085, DOI: 10.1016/j.fochx.2020.100085.
[48] HongyangCheng Hong, Jianrong Lin, Yanning Su, Denglong Chen, Xuelin Zheng, Hu Zhu, Green synthesis of soluble graphene in organic solvent via simultaneous functionalization and reduction of graphene oxide with urushiol, Materials Today Communications, , 2020, DOI: 10.1016/j.mtcomm.2020.100938
[49] Adere Tarekegne Habte, and Delele Worku Ayele, Synthesis and Characterization of Reduced Graphene Oxide (rGO) Started from Graphene Oxide (GO) Using the Tour Method with Different Parameters, Advances in Materials Science and Engineering, 2019, doi.org/10.1155/2019/5058163.
[50] ZulhelmiIsmail Green reduction of graphene oxide by plant extracts: A short review, Ceramics International 45(18). 2019. DOI: 10.1016/j.ceramint.2019.08.114.
[51] RanYin, Ping Shen, Zeyu Lu, A green approach for the reduction of graphene oxide by the ultraviolet/sulfite process, J Colloid Interface Sci, 2019. 15;550:110-116, doi: 0.1016/j.jcis.2019.04.073.
Published
2021-12-20
How to Cite
1.
Javanmardi N, Goodarzian DN, Xia M, Wang F. Green Synthesis and High-efficiency Method for Reduced Graphene Oxide by Urtica Dioica Extracts. AANBT [Internet]. 20Dec.2021 [cited 23Sep.2021];:37-6. Available from: https://dormaj.org/index.php/AANBT/article/view/430
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Articles